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Rubies are corundum with a dominant red body color. The color can be modified by both iron and trapped hole color centers. Unlike localized "intra-atomic" absorption of light which causes color for chromium and vanadium impurities, blue color in sapphires comes from intervalence charge transfer, which is the transfer of an electron from one transition-metal ion to another via the conduction or valence band.

Because of the valence change there is a specific change in energy for the electron, and electromagnetic energy is absorbed. The wavelength of the energy absorbed corresponds to yellow light.

When this light is subtracted from incident white light, the complementary color blue results. Sometimes when atomic spacing is different in different directions there is resulting blue-green dichroism.

Purple sapphires contain trace amounts of chromium and iron plus titanium and come in a variety of shades. Corundum that contains extremely low levels of chromophores is near colorless.

Completely colorless corundum generally does not exist in nature. If trace amounts of iron are present, a very pale yellow to green color may be seen.

However, if both titanium and iron impurities are present together, and in the correct valence states, the result is a blue color.

Intervalence charge transfer is a process that produces a strong colored appearance at a low percentage of impurity. Sapphires can be treated by several methods to enhance and improve their clarity and color.

Different atmospheres may be used. Upon heating, the stone becomes more blue in color, but loses some of the rutile inclusions silk.

The titanium from the rutile enters solid solution and thus creates with iron the blue color [24] The inclusions in natural stones are easily seen with a jeweler's loupe.

Evidence of sapphire and other gemstones being subjected to heating goes back at least to Roman times. Yogo sapphires do not need heat treating because their cornflower blue color is attractive out of the ground; they are generally free of inclusions , and have high uniform clarity.

As a result, it has remained a niche product, with a market that largely exists in the US. Lattice 'bulk' diffusion treatments are used to add impurities to the sapphire to enhance color.

This process was originally developed and patented by Linde Air division of Union Carbide and involved diffusing titanium into synthetic sapphire to even out the blue color.

Today, titanium diffusion often uses a synthetic colorless sapphire base. The color layer created by titanium diffusion is extremely thin less than 0.

Thus repolishing can and does produce slight to significant loss of color. Chromium diffusion has been attempted, but was abandoned due to the slow diffusion rates of chromium in corundum.

In the year , beryllium diffused "padparadscha" colored sapphires entered the market. Typically beryllium is diffused into a sapphire under very high heat, just below the melting point of the sapphire.

Initially c. Due to the small size of the beryllium ion, the color penetration is far greater than with titanium diffusion.

In some cases, it may penetrate the entire stone. Beryllium-diffused orange sapphires may be difficult to detect, requiring advanced chemical analysis by gemological labs e.

According to United States Federal Trade Commission guidelines, disclosure is required of any mode of enhancement that has a significant effect on the gem's value.

There are several ways of treating sapphire. Heat-treatment in a reducing or oxidizing atmosphere but without the use of any other added impurities is commonly used to improve the color of sapphires, and this process is sometimes known as "heating only" in the gem trade.

In contrast, however, heat treatment combined with the deliberate addition of certain specific impurities e. However, despite what the terms "heating only" and "diffusion" might suggest, both of these categories of treatment actually involve diffusion processes.

Sapphires are mined from alluvial deposits or from primary underground workings. Sapphires from different geographic locations may have different appearances or chemical-impurity concentrations, and tend to contain different types of microscopic inclusions.

Because of this, sapphires can be divided into three broad categories: classic metamorphic, non-classic metamorphic or magmatic, and classic magmatic.

Sapphires from certain locations, or of certain categories, may be more commercially appealing than others, [33] particularly classic metamorphic sapphires from Kashmir , Burma, or Sri Lanka that have not been subjected to heat-treatment.

Madagascar is the world leader in sapphire production as of specifically its deposits in and around the town of Ilakaka.

That area has been exploited for its sapphires started in , but it was practically abandoned just a few years later—because of the difficulties in recovering sapphires in their bedrock.

The sapphire deposits of Kashmir are well known in the gem industry, although their peak production took place in a relatively short period at the end of the nineteenth and early twentieth centuries.

Kashmir-origin contributes meaningfully to the value of a sapphire, and most corundum of Kashmir origin can be readily identified by its characteristic silky appearance and exceptional hue.

In October , Sotheby's Hong Kong achieved consecutive per-carat price records for Kashmir sapphires — first with the In , the French chemist Auguste Verneuil announced a process for producing synthetic ruby crystals.

Synthesis of blue sapphire came in , after chemical analyses of sapphire suggested to Verneuil that iron and titanium were the cause of the blue color.

Verneuil patented the process of producing synthetic blue sapphire in The key to the process is that the alumina powder does not melt as it falls through the flame.

Instead it forms a sinter cone on the pedestal. When the tip of that cone reaches the hottest part of the flame, the tip melts. Thus the crystal growth is started from a tiny point, ensuring minimal strain.

Next, more oxygen is added to the flame, causing it to burn slightly hotter. This expands the growing crystal laterally. At the same time, the pedestal is lowered at the same rate that the crystal grows vertically.

The alumina in the flame is slowly deposited, creating a teardrop shaped " boule " of sapphire material. This step is continued until the desired size is reached, the flame is shut off and the crystal cools.

The now elongated crystal contains a lot of strain due to the high thermal gradient between the flame and surrounding air.

To release this strain, the now finger-shaped crystal will be tapped with a chisel to split it into two halves. Due to the vertical layered growth of the crystal and the curved upper growth surface which starts from a drop , the crystals will display curved growth lines following the top surface of the boule.

This is in contrast to natural corundum crystals, which feature angular growth lines expanding from a single point and following the planar crystal faces.

Chemical dopants can be added to create artificial versions of the ruby, and all the other natural colors of sapphire, and in addition, other colors never seen in geological samples.

Artificial sapphire material is identical to natural sapphire, except it can be made without the flaws that are found in natural stones.

The disadvantage of the Verneuil process is that the grown crystals have high internal strains. Many methods of manufacturing sapphire today are variations of the Czochralski process , which was invented in by Polish chemist Jan Czochralski.

Synthetic sapphire is also produced industrially from agglomerated aluminum oxide, sintered and fused such as by hot isostatic pressing in an inert atmosphere, yielding a transparent but slightly porous polycrystalline product.

In , the world's production of synthetic sapphire was tons 1. Some sapphire-glass windows are made from pure sapphire boules that have been grown in a specific crystal orientation, typically along the optical axis, the c-axis, for minimum birefringence for the application.

The boules are sliced up into the desired window thickness and finally polished to the desired surface finish. Sapphire optical windows can be polished to a wide range of surface finishes due to its crystal structure and its hardness.

The surface finishes of optical windows are normally called out by the scratch-dig specifications in accordance with the globally adopted MIL-O specification.

The sapphire windows are used in both high pressure and vacuum chambers for spectroscopy , crystals in various watches , and windows in grocery store barcode scanners since the material's exceptional hardness and toughness makes it very resistant to scratching.

It is used for end windows on some high-powered laser tubes as its wide-band transparency and thermal conductivity allow it to handle very high power densities in the infra-red or UV spectrum without degrading due to heating.

Along with zirconia and aluminum oxynitride , synthetic sapphire is used for shatter resistant windows in armored vehicles and various military body armor suits, in association with composites.

One type of xenon arc lamp — originally called the "Cermax" and now known generically as the "ceramic body xenon lamp" — uses sapphire crystal output windows.

This product tolerates higher thermal loads and thus higher output powers when compared with conventional Xe lamps with pure silica window.

Thin sapphire wafers were the first successful use of an insulating substrate upon which to deposit silicon to make the integrated circuits known as silicon on sapphire or "SOS"; now other substrates can also be used for the class of circuits known more generally as silicon on insulator.

Besides its excellent electrical insulating properties, sapphire has high thermal conductivity. CMOS chips on sapphire are especially useful for high-power radio-frequency RF applications such as those found in cellular telephones , public-safety band radios, and satellite communication systems.

In one process, after single crystal sapphire boules are grown, they are core-drilled into cylindrical rods, and wafers are then sliced from these cores.

Wafers of single-crystal sapphire are also used in the semiconductor industry as substrates for the growth of devices based on gallium nitride GaN.

The use of sapphire significantly reduces the cost, because it has about one-seventh the cost of germanium.

Gallium nitride on sapphire is commonly used in blue light-emitting diodes LEDs. The first laser was made with a rod of synthetic ruby. Titanium-sapphire lasers are popular due to their relatively rare capacity to be tuned to various wavelengths in the red and near- infrared region of the electromagnetic spectrum.

They can also be easily mode-locked. In these lasers a synthetically produced sapphire crystal with chromium or titanium impurities is irradiated with intense light from a special lamp, or another laser, to create stimulated emission.

Monocrystalline sapphire is fairly biocompatible and the exceptionally low wear of sapphire—metal pairs has led to the introduction in Ukraine of sapphire monocrystals for hip joint endoprostheses.

From Wikipedia, the free encyclopedia. Gem variety of corundum. For other uses, see Sapphire disambiguation. The carat 85 g blue Logan Sapphire. Main article: silicon on sapphire.

Minerals portal. Journal of Applied Physics. Bibcode : JAP Gemological Institute of America Inc. Retrieved 27 October BBC News.

Billie Lotus Gemology. Lotus Gemology Co. Retrieved 5 November Houston Museum of Natural Science. Retrieved 6 November Scientific Publishing Company.

Colored Gemstones. Gemstone Press. Lazaro SoHo. Retrieved 25 November December Archived from the original on 28 June Retrieved 12 February Spring Retrieved 4 November Oxford: Oxford University Press.

GIA Laboratory, Bangkok. Retrieved 14 August Retrieved 5 January Los Angeles Times. March GK Magazine. Winter Causes of Color.

WebExhibits online museum. Gemmological Association of All Japan Co. Archived from the original on 9 March Retrieved 21 March Gemstone Enhancement.

January—February Gem Market News. Archived from the original on 27 June

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This season make a statement in our range of essential t-shirts, and pair them with your favourite denim - we have them in all cuts and fits, especially for you.

We bring to you a new, warmer and well-tailored menswear collection, made for your season's festive wardrobe.

Looking for affordable outfits that you can add to your child's everyday winter collection? Choose from a variety of cute dresses, tops, turtle necks, sweaters, hoodies and other fantastic items for trendy style.

This season, streets are popping big bags and sleek silhouettes. There is something special about climbing into bed and snuggling into fresh, comfy bedding after a long day!

From matching tops and bottoms to comfy separates, find an incredible range of sleepwear to suit your night-time style.

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Ready To Wear. Ready To Wear Bringing you a festive range of ensembles with sophisticated silhouettes, whimsical embroideries and prints painted with Sapphire colors, just for you!

Due to the small size of the beryllium ion, the color penetration is far greater than with titanium diffusion.

In some cases, it may penetrate the entire stone. Beryllium-diffused orange sapphires may be difficult to detect, requiring advanced chemical analysis by gemological labs e.

According to United States Federal Trade Commission guidelines, disclosure is required of any mode of enhancement that has a significant effect on the gem's value.

There are several ways of treating sapphire. Heat-treatment in a reducing or oxidizing atmosphere but without the use of any other added impurities is commonly used to improve the color of sapphires, and this process is sometimes known as "heating only" in the gem trade.

In contrast, however, heat treatment combined with the deliberate addition of certain specific impurities e. However, despite what the terms "heating only" and "diffusion" might suggest, both of these categories of treatment actually involve diffusion processes.

Sapphires are mined from alluvial deposits or from primary underground workings. Sapphires from different geographic locations may have different appearances or chemical-impurity concentrations, and tend to contain different types of microscopic inclusions.

Because of this, sapphires can be divided into three broad categories: classic metamorphic, non-classic metamorphic or magmatic, and classic magmatic.

Sapphires from certain locations, or of certain categories, may be more commercially appealing than others, [33] particularly classic metamorphic sapphires from Kashmir , Burma, or Sri Lanka that have not been subjected to heat-treatment.

Madagascar is the world leader in sapphire production as of specifically its deposits in and around the town of Ilakaka. That area has been exploited for its sapphires started in , but it was practically abandoned just a few years later—because of the difficulties in recovering sapphires in their bedrock.

The sapphire deposits of Kashmir are well known in the gem industry, although their peak production took place in a relatively short period at the end of the nineteenth and early twentieth centuries.

Kashmir-origin contributes meaningfully to the value of a sapphire, and most corundum of Kashmir origin can be readily identified by its characteristic silky appearance and exceptional hue.

In October , Sotheby's Hong Kong achieved consecutive per-carat price records for Kashmir sapphires — first with the In , the French chemist Auguste Verneuil announced a process for producing synthetic ruby crystals.

Synthesis of blue sapphire came in , after chemical analyses of sapphire suggested to Verneuil that iron and titanium were the cause of the blue color.

Verneuil patented the process of producing synthetic blue sapphire in The key to the process is that the alumina powder does not melt as it falls through the flame.

Instead it forms a sinter cone on the pedestal. When the tip of that cone reaches the hottest part of the flame, the tip melts.

Thus the crystal growth is started from a tiny point, ensuring minimal strain. Next, more oxygen is added to the flame, causing it to burn slightly hotter.

This expands the growing crystal laterally. At the same time, the pedestal is lowered at the same rate that the crystal grows vertically. The alumina in the flame is slowly deposited, creating a teardrop shaped " boule " of sapphire material.

This step is continued until the desired size is reached, the flame is shut off and the crystal cools. The now elongated crystal contains a lot of strain due to the high thermal gradient between the flame and surrounding air.

To release this strain, the now finger-shaped crystal will be tapped with a chisel to split it into two halves.

Due to the vertical layered growth of the crystal and the curved upper growth surface which starts from a drop , the crystals will display curved growth lines following the top surface of the boule.

This is in contrast to natural corundum crystals, which feature angular growth lines expanding from a single point and following the planar crystal faces.

Chemical dopants can be added to create artificial versions of the ruby, and all the other natural colors of sapphire, and in addition, other colors never seen in geological samples.

Artificial sapphire material is identical to natural sapphire, except it can be made without the flaws that are found in natural stones.

The disadvantage of the Verneuil process is that the grown crystals have high internal strains. Many methods of manufacturing sapphire today are variations of the Czochralski process , which was invented in by Polish chemist Jan Czochralski.

Synthetic sapphire is also produced industrially from agglomerated aluminum oxide, sintered and fused such as by hot isostatic pressing in an inert atmosphere, yielding a transparent but slightly porous polycrystalline product.

In , the world's production of synthetic sapphire was tons 1. Some sapphire-glass windows are made from pure sapphire boules that have been grown in a specific crystal orientation, typically along the optical axis, the c-axis, for minimum birefringence for the application.

The boules are sliced up into the desired window thickness and finally polished to the desired surface finish. Sapphire optical windows can be polished to a wide range of surface finishes due to its crystal structure and its hardness.

The surface finishes of optical windows are normally called out by the scratch-dig specifications in accordance with the globally adopted MIL-O specification.

The sapphire windows are used in both high pressure and vacuum chambers for spectroscopy , crystals in various watches , and windows in grocery store barcode scanners since the material's exceptional hardness and toughness makes it very resistant to scratching.

It is used for end windows on some high-powered laser tubes as its wide-band transparency and thermal conductivity allow it to handle very high power densities in the infra-red or UV spectrum without degrading due to heating.

Along with zirconia and aluminum oxynitride , synthetic sapphire is used for shatter resistant windows in armored vehicles and various military body armor suits, in association with composites.

One type of xenon arc lamp — originally called the "Cermax" and now known generically as the "ceramic body xenon lamp" — uses sapphire crystal output windows.

This product tolerates higher thermal loads and thus higher output powers when compared with conventional Xe lamps with pure silica window. Thin sapphire wafers were the first successful use of an insulating substrate upon which to deposit silicon to make the integrated circuits known as silicon on sapphire or "SOS"; now other substrates can also be used for the class of circuits known more generally as silicon on insulator.

Besides its excellent electrical insulating properties, sapphire has high thermal conductivity. CMOS chips on sapphire are especially useful for high-power radio-frequency RF applications such as those found in cellular telephones , public-safety band radios, and satellite communication systems.

In one process, after single crystal sapphire boules are grown, they are core-drilled into cylindrical rods, and wafers are then sliced from these cores.

Wafers of single-crystal sapphire are also used in the semiconductor industry as substrates for the growth of devices based on gallium nitride GaN.

The use of sapphire significantly reduces the cost, because it has about one-seventh the cost of germanium. Gallium nitride on sapphire is commonly used in blue light-emitting diodes LEDs.

The first laser was made with a rod of synthetic ruby. Titanium-sapphire lasers are popular due to their relatively rare capacity to be tuned to various wavelengths in the red and near- infrared region of the electromagnetic spectrum.

They can also be easily mode-locked. In these lasers a synthetically produced sapphire crystal with chromium or titanium impurities is irradiated with intense light from a special lamp, or another laser, to create stimulated emission.

Monocrystalline sapphire is fairly biocompatible and the exceptionally low wear of sapphire—metal pairs has led to the introduction in Ukraine of sapphire monocrystals for hip joint endoprostheses.

From Wikipedia, the free encyclopedia. Gem variety of corundum. For other uses, see Sapphire disambiguation. The carat 85 g blue Logan Sapphire.

Main article: silicon on sapphire. Minerals portal. Journal of Applied Physics. Bibcode : JAP Gemological Institute of America Inc.

Retrieved 27 October BBC News. Billie Lotus Gemology. Lotus Gemology Co. Retrieved 5 November Houston Museum of Natural Science. Retrieved 6 November Scientific Publishing Company.

Colored Gemstones. Gemstone Press. Lazaro SoHo. Retrieved 25 November December Archived from the original on 28 June Retrieved 12 February Spring Retrieved 4 November Oxford: Oxford University Press.

GIA Laboratory, Bangkok. Retrieved 14 August Retrieved 5 January Los Angeles Times. March GK Magazine. Winter Causes of Color. WebExhibits online museum.

Gemmological Association of All Japan Co. Archived from the original on 9 March Retrieved 21 March Gemstone Enhancement. January—February Gem Market News.

Archived from the original on 27 June Retrieved 2 January Gubelin Gem Labs. American Gem Trade Association. Rapaport Diamond Report.

Hudson Institute of Mineralogy. Use with care: managing Australia's natural resources in the twenty-first century. Madagascar sapphire. Archived from the original on 16 April Franklin, North Carolina Chamber of Commerce.

Retrieved 11 August Joel; Clark, Donald. Retrieved 12 September Archived from the original on 23 March September Annales de Chimie et de Physique.

Retrieved 18 June Journal of the American Ceramic Society. LED Inside. TrendForce Corp. International Gem Society.

Retrieved 25 October Crystal growth technology PDF. Chichester, West Sussex: J. Dobrovinskaya; Leonid A.

Lytvynov; Valerian Pishchik Sapphire: Materials, Manufacturing, Applications. Biology: Concepts and Applications.

Corning, N. May

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